Bauxite Beneficiation Electrostatic

एल्यूमीनियम धरती मा पाइने भन्दा साधारण धातु तत्व हो, totaling about 8% पृथ्वी पाप्रो को. तथापि, aluminum as an element is reactive and therefore does not occur naturallyit needs to be refined to produce aluminum metal. एल्यूमीनियम शोधन लागि प्राथमिक सुरूवात सामाग्री bauxite छ, एल्यूमीनियम को संसारको मुख्य व्यापारिक स्रोत. Bauxite is a sedimentary rock, and consists mostly of the aluminium minerals gibbsite (अल(ओह)3), boehmite (ग-ALO(ओह)) र diaspore (एक-ALO(ओह)), and is usually mixed with the two iron oxides goethite and hematite, the aluminium clay mineral kaolinite and small amounts of anatase (TiO2) and/or ilmenite (FeTiO3).

bauxite beneficiation

Bauxite जम्मा प्रसार विश्वव्यापी हो, ज्यादातर ट्रपिकल वा Subtropical क्षेत्रहरु मा निरन्तर. Although proven reserves of bauxite are expected to last for many years, आर्थिक पहुँच गर्न सकिन्छ कि रिजर्व गुणस्तर घट्दो छ. refiners लागि, who are in the business of bauxite processing to make alumina, र अन्ततः एल्यूमीनियम धातु, यो दुवै वित्तीय र पर्यावरणीय असरहरू एक चुनौती हो.

The process to refine metallurgical bauxite into alumina involves the following inputs:

  • Bauxite ore
  • Caustic sodasodium hydroxide chemical (NaOH)
  • Energy (refining process requires both heat and pressure)
  • Fresh water

The following outputs are generated:

  • एल्युमिना (Al2O3)
  • Alumina refinery residues (ARR) or Red mud
bauxite processing

The most widely used chemical process of refining bauxite into alumina, बायर प्रक्रिया, involves dissolving the Al2O3 out of the bauxite rock with caustic soda (NaOH) at elevated temperature and pressure. The Al2O3 fraction of the bauxite is dissolved into solution, to later be precipitated out as alumina. तथापि, a high-grade bauxite contains up to 60% Al2O3, and many operating bauxite deposits are well below this, रूपमा कम रूपमा कहिले काँही 30-40% Al2O3. Because the desired product is a high purity Al2O3, को bauxite बाँकी आक्साइड (Fe2O3, SiO2, TiO2, Organic material) are separated from the Al2O3 and rejected as alumina refinery resides (ARR) or red mud. सामन्यतया, तल्लो गुणवत्ता bauxite (ie lower Al2O3 content) the more red mud is generated per ton of alumina product. साथै, even some Al2O3 bearing minerals, बाहेकलाई kaolinite, produce un-desirable side reactions during the refining process and lead to an increase in red mud generation, राम्रो महंगा कास्टिक सोडा रासायनिक एक हानि रूपमा, को bauxite शोधन प्रक्रिया मा एक ठूलो चल लागत.

रातो माटोको वा ARR देखि एक ठूलो र-जा एल्यूमीनियम उद्योग लागि चुनौती प्रतिनिधित्व. रातो माटोको को शोधन प्रक्रिया देखि महत्वपूर्ण अवशिष्ट कास्टिक रासायनिक बाँकी समावेश, र अत्यधिक alkaline छ, अक्सर एक पीएच संग 10 - 13. It is generated in large volumes worldwideaccording to the USGS, अनुमानित वैश्विक अल्युमिना उत्पादन थियो 121 लाख टन मा 2016. This likely resulted in more than 150 एउटै अवधिमा उत्पन्न रातो माटोको को लाख टन. निरन्तर अनुसन्धान बावजुद, रातो माटोको हाल लाभदायक पुन प्रयोग गर्न केही व्यावसायिक कारगर बाटो छ. यो रातो माटोको को धेरै सानो beneficially छ कि अनुमान गरिएको छ पुन प्रयोग विश्वव्यापी. Instead the red mud is pumped from the alumina refinery into storage impoundments or landfills, जहाँ यसलाई भण्डारण र ठूलो लागत अनुगमन गरिएको छ.

महंगा कास्टिक सोडा को हानि (NaOH) and the generation of red mud are both related to the quality of the bauxite used in the refining process. सामन्यतया, the lower the Al2O3 content of the bauxite, उत्पन्न हुनेछ भन्ने ठूलो रातो माटोको को मात्रा, as the non-Al2O3 phases are rejected as red mud. साथै, the higher the kaolinite or reactive silica content of the bauxite, अधिक रातो माटोको उत्पन्न हुनेछ. The reactive silica content not only increases the volume of red mud, but also consumes caustic soda reagent and reduces the yield of Al2O3 recovered from the bauxite. त्यसैले, there is both an economic and environmental argument to be made for improving the quality of bauxite prior to refining.

को STET ड्राई अलग प्रक्रिया प्रस्ताव उत्पादकहरु वा bauxite refiners गुणस्तर सुधार गर्न bauxite अयस्क को पूर्व-बायर-प्रक्रिया अपग्रेड प्रदर्शन गर्ने मौका bauxite. यो दृष्टिकोण धेरै लाभ छ:

  • कारण इनपुट प्रतिक्रियाशील सिलिका कम द्वारा कास्टिक सोडा को कम खपत गर्न रिफाइनरी को सञ्चालन लागत मा कमी.
  • Savings in energy during refining due to lower volume of inert oxides (Fe2O3, TiO2, Non-reactive SiO2) bauxite संग प्रवेश. Smaller mass flow of bauxite to refinery results in less energy to heat and pressurize.
  • Reduction in red mud generation volume (ie – अल्युमिना अनुपात रातो माटोको) by removing reactive silica and inert oxides.
  • Tighter control over input bauxite quality to refinery reduces process upsets and allows refiners to target ideal reactive silica level to maximize impurity rejection.
  • Improved quality control over bauxite feed to refinery reduces process upsets, maximizes uptime and productivity.
  • Reduction in red mud volume translates into less treatment and disposal costs and better utilization of existing landfills.
  • रातो माटोको विपरीत, सुक्खा electrostatic प्रक्रिया बाट tailings कुनै रसायन समावेश र दीर्घकालीन पर्यावरणीय भण्डारण दायित्व प्रतिनिधित्व छैन.
  • रातो माटोको विपरीत, dry by-products/tailings from a bauxite processing operation can be utilized in cement manufacture as there is no requirement to remove the sodium, जो सिमेन्ट निर्माण गर्न हानिकारक छ. वास्तबमा – Bauxite is already a common raw material for Portland cement manufacturing.
  • Extend operating life of existing bauxite mine by improving quarry utilization and maximizing recovery.
  • STET is a low operating cost, high throughput continuous process. No water or chemicals required.

संक्षिप्तमा, bauxite उत्पादकहरु र refiners लागि मूल्य उत्पन्न गर्न STET विभाजक प्रस्ताव अवसर संग ड्राई प्रक्रिया. bauxite पूर्व शोधन गर्न को पूर्व-प्रक्रिया लागत रासायनिक कम गर्नेछ, उत्पन्न रातो माटोको को मात्रा कम र प्रक्रिया upsets कम.

सन्दर्भ:

  • Raju, K. एस. 2009. Bauxite Resources in India, Aluminum Association of India, Bangalore, भारत
  • Hausberg, जे, Happel, U., Meyer, F.M. 1999. Bauxite Quality and its Effect on Red Mud Generated during Alumina Production, 1999, International Symposium on Mine Environmental and Economic Issues, युक्रेन, जुन 1999.
  • USGS Minerals Yearbook 2016, Volume I, Commodity Report, Bauxite and Alumina 2016.
  • Bagshaw, एक. एन, The Aluminum Story, Bauxite to Alumina: The Bayer Process, An Introductory Text, अक्टोबर 2017
  • Aboagye, ए, Kildea, जे, La, टी, and Phillips, E., Management and Control of Silica in the Bayer Process, Proceedings of the 9th International Alumina Quality Workshop, 2012, पृ 93-97

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