Aluminium yisona esikhulunywa abantu abaningi isici metal wathola Emhlabeni, ingqikithi mayelana 8% uqweqwe eMhlabeni. Nokho, aluminum as an element is reactive and, Ngakho-ke, does not occur naturally – it needs to be refined to produce aluminum metal. Okuxhunyanwa sokuqala zethu ezingokwenyama aluminium yokucwenga kuyinto bauxite, umthombo emhlabeni main commercial-aluminiyamu. Bauxite is a sedimentary rock and consists mostly of the aluminum minerals gibbsite (Al(OH)3), boehmite (c-Alo(OH)), futhi diaspore (a-Alo(OH)), futhi ivame ukuxutshwa nezinsimbi ezimbili ze-oxide goethite ne-hematite, the aluminum clay mineral kaolinite and small amounts of anatase (TiO2) kanye / noma ilmenite (FeTiO3).
ezifakwa bauxite kukhona ukusabalala emhlabeni wonke, ikakhulukazi okwenzeka ezindaweni ezinamahlathi emvula noma nakwezifudumele. Yize okulondoloziwe okutholakele kwe-bauxite kulindeleke ukuthi kuhlale iminyaka eminingi, izinga lezokuvikela ukuthi kungenziwa kwezomnotho afinyelelwe liyancipha. For refiners who are in the business of bauxite processing to make alumina and, eventually, aluminum metal, lokhu kuyinselele kokubili nemithelela zezimali kanye nezemvelo.
The process of refining metallurgical bauxite into alumina involves the following inputs:
Imiphumela elandelayo iyenziwa:
Inqubo esetshenziswa kakhulu yamakhemikhali yokuhlanza i-bauxite ibe yi-alumina, inqubo yeBayer, kufaka phakathi ukucibilika kwe-Al2O3 edwaleni le-bauxite nge-caustic soda (NaOH) emazingeni okushisa aphakeme nengcindezi. The Al2O3 fraction of the bauxite is dissolved into a solution, which is later precipitated out as alumina. Nokho, high-grade bauxite contains up to 60% Al2O3, futhi imali eningi esebenza nge-bauxite ingaphansi kwalokhu, ngezinye izikhathi njengoba low 30-40% Al2O3. Because the desired product is a high-purity Al2O3, the oxides ezisele bauxite (Fe2O3, SiO2, TiO2, Izinto eziphilayo) zihlukaniswe ne-Al2O3 futhi zenqatshwa njengokuhlala indawo yokuhlanza i-alumina (Fika) noma udaka obomvu. Ngenjwayelo, the lower the quality of the bauxite (okuyi, lower Al2O3 content), udaka obomvu xaxa lwenziwa ithoni ngayinye yomkhiqizo we-alumina. Ngaphezu kwalokho, even some Al2O3-bearing minerals, ephawuleka kaolinite, ukukhiqiza engathandeki ohlangothini ukusabela phakathi kucwengisiswa futhi kuholele ukwanda obomvu udaka isizukulwane, kanye nokulahlekelwa ezibizayo caustic soda chemical, a high variable cost in the bauxite refining process.
Red mud, or ARR, represents a large and on-going challenge for the aluminum industry. Red mud contains significant residual caustic chemical leftover from the refining process and is highly alkaline, ngokuvamile line-pH 10 - 13. It is ekhiqizwa kuleli lemiqulu emikhulu emhlabeni wonke - ngokuvumelana USGS, Kulinganiselwa ukukhiqizwa alumina global kwaba 121 amathani ayizigidi ezingu-e 2016. Lokhu kungenzeka kuholele kokunye 150 amathani ayizigidi ezingu udaka olubomvu elakhiwe phakathi nenkathi efanayo. Naphezu ucwaningo okuqhubekayo, udaka olubomvu okwamanje Imbalwa izindlela elizimele ukuba nenzuzo kabusha ukusetshenziswa. It is estimated that very little red mud is beneficially re-used worldwide. Kunalokho, odakeni obomvu akhishwa endaweni yokuhluza alumina kusitoreji impoundments noma landfills, where it is stored and monitored at a high cost.
Ukulahleka ezibizayo soda caustic (NaOH) kanye nesizukulwane sodaka obomvu kuhlobene nekhwalithi ye-bauxite esetshenziselwa inqubo yokucoca. Ngenjwayelo, engezansi okuqukethwe kwe-Al2O3 kwe-bauxite, elikhulu ivolumu udaka olubomvu ukuthi lizokhiqizwa, njengoba izigaba ezingezona i-Al2O3 zenqatshwa njengodaka obomvu. Ngaphezu kwalokho, ukuphakama kokuqukethwe kwe-kaolinite noma okusebenzayo kwe-bauxite, odakeni elibomvu ngaphezulu lizokhiqizwa. The reactive silica content not only increases the volume of red mud but also consumes caustic soda reagent and reduces the yield of Al2O3 recovered from the bauxite. Ngakho-ke, both an economic and environmental argument must be made to improve the quality of bauxite prior to refining.
The STET dry separation process offers bauxite producers or bauxite refiners an opportunity to perform pre-bayer-process upgrading of bauxite ore to improve the quality. Le ndlela kunezinzuzo eziningi:
Ngokufigqiwe, ukucutshungulwa ezomile kanye namathuba STET isihlukanisi izipesheli ukukhiqiza value kubakhiqizi bauxite futhi refiners. Pre-ukucutshungulwa bauxite ngaphambi yokucwenga kuzonciphisa izindleko chemical, wehlise ivolumu udaka olubomvu elakhiwe futhi unciphise inqubo izinkinga.
Izinkomba: