Boksit Beneficiation Elektwostatik

Aliminyom se eleman nan metal ki pi komen yo te jwenn sou late, totalize sou 8% kwout late. Sepandan, aliminyom kom yon eleman se reyaktif ak se poutet sa pa rive natirelman – li bezwen rafine pou pwodwi metal aliminyom. Prensipal materyel la komanse pou raffinage aliminyom se Boksit, sous prensipal komesyal mondyal la nan aliminyom. Boksit se yon woch sedimante, e konsiste sitou nan mineral aliminyom yo gibbsite (Al(o)3), maren (γ-AlO(o)) e dyaspora (α-AlO(o)), e anjeneral melanje ak de oksid fe yo goethite ak emaye, kaolinite mineral la aliminyom ajil ak ti kantite ananataz (TiO2) e/oswa ilmenite (FeTiO3).

bauxite beneficiation

Depo Boksit yo gaye atrave lemond, sitou rive nan rejyon twopikal oswa subtropical. Malgre ke pwouve rezev nan Boksit yo espere pou denye pou anpil ane, bon jan kalite a nan rezev yo ki ka ekonomikman jwenn akse se dekline. Pou pirifikate, who are in the business of bauxite processing to make alumina, e evantyelman aliminyom metal, sa a se yon defi ak tou de enplikasyon finansye ak anviwonman.

Pwosesis la rafine metalurji Boksit nan aliminyom enplike entrain sa yo:

  • Boksit minre
  • Mordan soda – sodyom dwoksid chimik (Naoh)
  • Enèji (pwosesis raffinage mande tou de chale ak presyon)
  • Dlo fre

Outputs sa yo pwodwi:

  • Aliminyom (Al2O3)
  • Alumina rafineri résidus (ARR) oswa labou wouj
bauxite processing

Pwosesis chimik ki pi lajman itilize nan raffinage Boksit nan alumina, pwosesis Bayer la, enplike nan Al2O3 soti nan woch la Boksit ak soda rilan (Naoh) nan tanperati ki wo ak presyon. Fraksyon al2O3 nan Boksit la se fonn nan solisyon, to later be precipitated out as alumina. Sepandan, a high-grade bauxite contains up to 60% Al2O3, and many operating bauxite deposits are well below this, occasionally as low as 30-40% Al2O3. Because the desired product is a high purity Al2O3, the remaining oxides in the bauxite (Fe2O3, Sio2, TiO2, Organic material) are separated from the Al2O3 and rejected as alumina refinery resides (ARR) or red mud. In general, the lower quality the bauxite (ie lower Al2O3 content) the more red mud is generated per ton of alumina product. epi tou, even some Al2O3 bearing minerals, notably kaolinite, produce un-desirable side reactions during the refining process and lead to an increase in red mud generation, as well as a loss of expensive caustic soda chemical, a large variable cost in the bauxite refining process.

Red mud or ARR represents a large and on-going challenge for the aluminum industry. Red mud contains significant residual caustic chemical leftover from the refining process, and is highly alkaline, often with a pH of 10 - 13. It is generated in large volumes worldwideaccording to the USGS, estimated global alumina production was 121 million tons in 2016. This likely resulted in more than 150 million tons of red mud generated during the same period. Despite ongoing research, red mud currently has few commercially viable paths to beneficial re-use. It is estimated that very little of red mud is beneficially re-used worldwide. Instead the red mud is pumped from the alumina refinery into storage impoundments or landfills, where it is stored and monitored at large cost.

The loss of expensive caustic soda (Naoh) ak jenerasyon an nan labou wouj yo tou de ki gen rapo ak bon jan kalite a nan Boksit yo itilize nan pwosesis la raffinage. In general, pi ba a Al2O3 kontni nan Boksit la, pi gwo volim labou wouj ki pral pwodwi, kom faz ki pa Al2O3 yo rejte kom labou wouj. epi tou, pi wo a kaolinite oswa reyaktif silica kontni nan Boksit la, yo pral pwodwi plis labou wouj. Kontni an silica reyaktif pa selman ogmante volim nan labou wouj, Men tou manje rilan soda reyaktif ak redui sede a nan Al2O3 refe soti nan Boksit la. Se poutet sa, gen tou de yon agiman ekonomik ak anviwonman yo dwe fet pou amelyore bon jan kalite Boksit anvan raffinage.

The STET dry separation process offers bauxite producers or bauxite refiners an opportunity to perform pre-Bayer-process upgrading of bauxite ore to improve the quality. This approach has many benefits:

  • Reduction in operating cost of refinery due to lower consumption of caustic soda by reducing input reactive silica.
  • Savings in energy during refining due to lower volume of inert oxides (Fe2O3, TiO2, Non-reactive SiO2) entering with bauxite. Smaller mass flow of bauxite to refinery results in less energy to heat and pressurize.
  • Reduction in red mud generation volume (iered mud to alumina ratio) by removing reactive silica and inert oxides.
  • Tighter control over input bauxite quality to refinery reduces process upsets and allows refiners to target ideal reactive silica level to maximize impurity rejection.
  • Improved quality control over bauxite feed to refinery reduces process upsets, maximizes uptime and productivity.
  • Reduction in red mud volume translates into less treatment and disposal costs and better utilization of existing landfills.
  • Unlike red mud, tailings from a dry electrostatic process contain no chemicals and do not represent a long-term environmental storage liability.
  • Unlike red mud, dry by-products/tailings from a bauxite processing operation can be utilized in cement manufacture as there is no requirement to remove the sodium, which is detrimental to cement manufacture. In factBauxite is already a common raw material for Portland cement manufacturing.
  • Extend operating life of existing bauxite mine by improving quarry utilization and maximizing recovery.
  • STET is a low operating cost, debi segonde pwosesis kontinyel. Pa gen dlo oswa pwodwi chimik ki nesese.

An rezime, pwosesis sek ak separate STET a ofri opotinite pou jenere vale pou pwodikte Boksit ak pirifikate. Pre-pwosesis la nan Boksit anvan raffinage ap redwi depans chimik, pi ba volim labou wouj la pwodwi ak minimize pwosesis ove san.

Referans:

  • Raju, SOUFRI. S. 2009. Resous Boksit nan peyi Zend, Asosyasyon Aliminyom nan peyi Zend, Bangalore, End
  • Hausberg, J., Happel, U., Meyer, F.M. 1999. Boksit bon jan kalite ak Efe li yo sou labou wouj pwodwi pandan pwodiksyon Alumina, 1999, Senpozyom entenasyonal sou anviwonman mwen ak pwoblem ekonomik, Ikrèn, Jen 1999.
  • USGS mineral liv souvni lekol 2016, Volim mwen, Rapo Komodite, Boksit ak Alumina 2016.
  • Bagshaw, YON. N., Istwa a Aliminyom, Boksit pou Alumina: Pwosesis bayer la, Yon teks entwodiksyon, Oktòb 2017
  • Aboagye, Yon., Kildea, J., La, T., e Phillips, E., Jesyon ak kontwol nan Silica nan pwosesis la Bayer, Proceedings of the 9th International Alumina Quality Workshop, 2012, pp 93-97

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