Triboelectrostatic Beneficiation tanah yang dipenuhi dan Abu Terbang Ponded

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Triboelectrostatic Beneficiation of

Land Filled and Ponded Fly Ash

By Lewis Baker, Abhishek Gupta, Stephen Gasiorowski, and Frank Hrach

The American Coal Ash Association (ACAA) annual survey of production and use of coal fly ash reports that between 1966 Dan 2011, over 2.3 billion short tons of fly ash have been produced by coal-fired utility boilers.1 Of this amount approximately 625 million tons have been beneficially used, mostly for cement and concrete production. Walau bagaimanapun, the remaining 1.7+ billion tons are primarily found in landfills or filled ponded impoundments. While utilization rates for freshly generated fly ash have increased considerably over recent years, with current rates near 45%, Kira 40 million tons of fly ash continue to be disposed of annually. While utilization rates in Europe have been much higher than in the US, considerable volumes of fly ash have also been stored in landfills and impoundments in some European countries.

Tempahan, interest in recovering this disposed material has increased, partially due to the demand for high-quality fly ash for concrete and cement production during a period of reduced production as coal-fired power generation has decreased in Europe and North America. Concerns about the long-term environmental impact of such landfills are also prompting utilities to find beneficial use applications for this stored ash.

LAND FILLED ASH QUALITY AND REQUIRED BENEFICIATION

While some of this stored fly ash may be suitable for beneficial use as initially excavated, the vast majority will require some processing to meet quality standards for cement or concrete production. Since the material has been typically wetted to enable handling and compaction while avoiding airborne dust generation, drying and deagglomeration is a necessary requirement for use in concrete since concrete producers will want to continue the practice of batching fly ash as a dry, serbuk halus. Walau bagaimanapun, assuring the chemical composition of the ash meets specifications, most notably the carbon content measured as loss-on-ignition (LOI), is a greater challenge. As fly ash utilization has increased in the last 20+ tahun, most “in-spec” ash has been beneficially used, and the off-quality ash disposed. Thus, LOI reduction will be a requirement for utilizing the vast majority of fly ash recoverable from utility impoundments.

LOI REDUCTION BY TRIBOELECTRIC SEPARATION

While other researchers have used combustion techniques and flotation processes for LOI reduction of recovered landfilled and ponded fly ash, Peralatan ST & Technologies (STET) has found that its unique triboelectrostatic belt separation system, long used for beneficiation of freshly generated fly ash, is also effective on recovered ash after suitable drying and deagglomeration.

STET researchers have tested the triboelectrostatic separation behavior of dried landfilled ash from several fly ash landfills in the Americas and Europe. This recovered ash separated very similarly to freshly generated ash with one surprising difference: the particle charging was reversed from that of fresh ash with the carbon charging negative in relation to the mineral.2 Other researchers of electrostatic separation of fly ash carbon have also observed this phenomena.3,4,5 The polarity of the STET triboelectrostatic separator can easily be adjusted to allow rejection of negatively charged carbon from dried landfilled fly ash sources. No special modifications to the separator design or controls are necessary to accommodate this phenomena.

TECHNOLOGY OVERVIEW – FLY ASH CARBON SEPARATION

In the STET carbon separator (Rajah 1), material is fed into the thin gap between two parallel planar electrodes. Zarah-zarah dicaj secara triboelektik oleh kenalan interparticle. The positively charged carbon and the negatively charged mineral (in freshly generated ash that has not been wetted and dried) are attracted to opposite electrodes. The particles are then swept up by a continuous moving belt and conveyed in opposite directions. Tali pinggang menggerakkan zarah bersebelahan setiap elektrod ke arah hujung bertentangan pemisah. Kelajuan tali pinggang yang tinggi juga membolehkan kendandahan yang sangat tinggi, selewat-lewatnya 36 tonnes per hour on a single separator. Jurang kecil, high voltage field, aliran semasa kaunter, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features

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of the STET separator. Dengan mengawal pelbagai parameter proses, seperti kelajuan tali pinggang, titik suapan, dan kadar suapan, proses STET menghasilkan abu terbang LOI rendah pada kandungan karbon kurang daripada 1.5 untuk 4.5% from feed fly ashes ranging in LOI from 4% kepada lebih 25%.

Fig. 1 STET Separator processing dried, landfilled Abu Terbang

The separator design is relatively simple and compact. Mesin yang direka untuk memproses 40 tan sejam adalah kira-kira 30 Ft. (9 m.) panjang, 5 Ft. (1.5 m.) Luas, Dan 9 Ka., m (2.75 m.) Tinggi. Tali pinggang dan penggelek yang berkaitan adalah satu-satunya bahagian yang bergerak. Elektrod-elektrod adalah alat tulis dan terdiri daripada bahan tahan lama yang sesuai. The belt is made of non-conductive plastic. The separator’s power consumption is about 1 kilowatt-hour per tonne of material processed with most of the power consumed by two motors driving the belt.

Proses ini sama sekali Kering, requires no additional materials other than the fly ash and produces no waste water or air emissions. Bahan-bahan yang pulih terdiri daripada Abu Terbang mengurangkan kandungan karbon kepada tahap yang sesuai untuk digunakan sebagai satu Tambah pozzolanic dalam konkrit, and a high carbon fraction useful as fuel. Penggunaan kedua-dua aliran produk menyediakan 100% penyelesaian kepada masalah penjualan Abu Terbang.

PROASH® RECOVERED FROM LAND FILLS

Empat sumber ash telah diperolehi daripada tapak pelupusan: sample A from a power plant located in the United Kingdom and samples B, C, dan D dari Amerika Syarikat. Semua sampel ini terdiri daripada Abu dari pembakaran arang batu bituminous oleh dandang utiliti yang besar. Disebabkan oleh intermingling bahan di tapak pelupusan sampah di, sebarang maklumat lanjut boleh didapati mengenai keadaan sumber atau pembakaran arang batu yang tertentu.

Sampel seperti yang diterima oleh STET terkandung di antara 15% Dan 27% water as is typical for landfilled material. The samples also contained varying amounts of large >1/8 inci (~3 mm) bahan. Untuk menyediakan sampel untuk pengasingan karbon, runtuhan besar adalah dipenuhi dengan pemeriksaan dan sampel kemudiannya dikeringkan dan deagglomerated sebelum beneficiation karbon. Several methods for drying/deagglomeration have been evaluated at the pilot-scale in order to optimize the overall process. STET has selected an industrially proven, feed processing system that offers simultaneous drying and deagglomeration necessary for effective electrostatic separation. A general process flow sheet is presented in Figure 2.

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Rajah 2: Process Flow Diagram

Hartanah-hartanah sampel disediakan telah baik dalam lingkungan Abu terbang yang diperolehi secara langsung dari dandang biasa utiliti. Sifat-sifat yang paling relevan untuk kedua-dua pemisah suapan dan produk diringkaskan dalam Jadual 2 bersama-sama dengan produk pulih.

PENGASINGAN KARBON

Carbon reduction trials using the STET triboelectric belt separator resulted in very good recovery of low LOI products from all four landfill fly ash sources. The reverse charging of the carbon as discussed above did not degrade the separation in any way as compared to processing fresh ash.

The properties of the low LOI fly ash recovered using the STET process for both freshly collected ash from the boiler and ash recovered from the landfill is summarized in Table 1. The results show that the product quality for ProAsh® produced from landfilled material is equivalent to product produced from fresh fly ash sources.

Jadual 1: Properties of feed and recovered ProAsh®.

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PRESTASI DALAM KONKRIT

The properties of the ProAsh® generated from the reclaimed landfill material were compared to that of ProAsh® produced from fresh fly ash generated by the utility boilers from the same location. The processed reclaimed ash meets all the specifications of ASTM C618 and AASHTO M250 standards. The following table summarizes the chemistry for samples from two of the sources showing the insignificant difference between the fresh and reclaimed material.

Jadual 2: Ash Chemistry of low LOI ash.

Strength development of a 20% substitution of the low LOI fly ash in a mortar containing 600 lb cementitious/ yd3 (Lihat Jadual 3 below) showed the ProAsh® product derived from landfilled ash yielded mortars with strength comparable to mortars produced using ProAsh® from fresh fly ash produced at the same location. The end product of the beneficiated reclaimed ash would support high end uses in the concrete industry consistent with the highly valuable position ProAsh® enjoys in the markets it currently serves.

Jadual 3: Compressive strength of mortar cylinders.

PROCESS ECONOMICS

The availability of low cost natural gas in the USA greatly enhances the economics of drying processes, including the drying of wetted fly ash from landfills. Jadual 4 summarizes the fuel costs for operations in the USA for 15% Dan 20% moisture contents. Typical inefficiencies of drying are included in the calculated values. Costs are based on the mass of material after drying. The incremental costs for drying fly ash for STET triboelectrostatic separation processing are relatively low.

Jadual 4: Drying costs on basis of dried mass.

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Even with the addition of feed drying costs, the STET separation process offers a low cost, industrially proven, process for LOI reduction of landfilled fly ash. The STET process for reclaimed fly ash is one-third to one-half of the capital cost compared to combustion based systems. The STET process for reclaimed fly ash also has significantly lower emissions to the environment compared to combustion or flotation based systems. Since the only additional air emission source to the standard STET process installation is a natural gas-fired dryer, permitting would be relatively simple.

RECOVERED FUEL VALUE OF HIGH-CARBON FLY ASH

In addition to the low carbon product for use in concrete, brand named ProAsh®, the STET separation process also recovers otherwise wasted unburned carbon in the form of carbon-rich fly ash, branded EcoTherm™. EcoTherm™ has significant fuel value and can easily be returned to the electric power plant using the STET EcoTherm™ Return system to reduce the coal use at the plant. When EcoTherm™ is burned in the utility boiler, the energy from combustion is converted to high pressure / high temperature steam and then to electricity at the same efficiency as coal, typically 35%. The conversion of the recovered thermal energy to electricity in ST Equipment & Technology LLC EcoTherm™ Return system is two to three times higher than that of the competitive technology where the energy is recovered as low-grade heat in the form of hot water which is circulated to the boiler feed water system. EcoTherm™ is also used as a source of alumina in cement kilns, displacing the more expensive bauxite which is usually transported long distances. Utilizing the high carbon EcoTherm™ ash either at a power plant or a cement kiln, maximizes the energy recovery from the delivered coal, reducing the need to mine and transport additional fuel to the facilities.

STET’s Talen Energy Brandon Shores, SMEPA R.D. Morrow, NBP Belledune, RWEnpower Didcot, EDF Energy West Burton, RWEnpower Aberthaw, and the Korea South-East Power fly ash plants all include EcoTherm™ Return systems.

STET ASH PROCESSING FACILITIES

STET’s separation process has been used commercial since 1995 for fly ash beneficiation and has generated over 20 million tons of high quality fly ash for concrete production. Controlled low LOI fly ProAsh®, is currently produced with STET’s technology at eleven power stations throughout the U.S., Kanada, the U.K., Poland, and Republic of Korea. ProAsh® Abu Terbang telah diluluskan untuk digunakan oleh pihak berkuasa lebuh raya negeri lebih daripada dua puluh, juga kerana banyak agensi spesifikasi. ProAsh® juga telah diperakui di bawah Persatuan piawaian Kanada dan EN 450:2005 standard kualiti di Eropah. Ash kemudahan pemprosesan menggunakan teknologi STET disenaraikan dalam Jadual 5.

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Jadual 5. Kemudahan pemprosesan Abu Terbang menggunakan teknologi pemisahan STET

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CONCLUSIONS

After suitable scalping of large material, drying, and deagglomeration, fly ash recovered from utility plant landfills can be reduced in carbon content using the commercialized STET triboelectric belt separator. The quality of the fly ash product, ProAsh® using the STET system on reclaimed landfill material is equivalent to ProAsh® produced from fresh feed fly ash. The ProAsh® product is very well suited and proven in concrete production. The recovery and beneficiation of landfilled ash will provide a continuing supply of high quality ash for concrete producers in spite of the reduced production of “fresh” ash as coal-fired utilities reduce generation. Additionally, power plants that need to remove ash from landfills to meet changing environmental regulations will be able to utilize the process to alter a waste product liability into a valuable raw material for concrete producers. The STET separation process with feed pre-processing equipment for drying and deagglomerating landfilled fly ash is an attractive option for ash beneficiation with significantly lower cost and lower emissions compared to other combustion and flotation based systems.

Rujukan

[1]American Coal Ash Coal Combustion products and Use Statistics: http://www.acaa- usa.org/Publications/Production-Use-Reports.

[2]ST internal report, Ogos 1995.

[3]Li,T.X,. Schaefer, J.L., Ban, H., Neathery, J.K., and Stencel, J.M. Dry Beneficiation Processing of Combustion Fly Ash, Proceedings of the DOE Conference on Unburned Carbon on Utility Fly Ash, Mungkin 19 20, Pittsburgh, PA, 1998.

[4]Baltrus, J.P., Diehl, J.R., Soong, Y., Sands, W. Triboelectrostatic separation of fly ash and charge reversal, Fuel 81, (2002) pp.757-762.

[5]Cangialosi, F., Notarnicola, M., Liberti, L, Stencel, J. The role of weathering on fly ash charge distribution during triboelectrostatic beneficiation, Journal of Hazardous Materials, 164 (2009) pp.683-688.

AUTHORS

Lewis Baker is the European Technical Support Manager for ST Equipment & Teknologi (STET) based in the United Kingdom

Abhishek Gupta is a Process Engineer based at the Separation Technologies pilot plant and lab facility, STET Technical Center, 101 Hampton Ave, Needham MA 02494 +1-781-972-2300

Dr. Stephen Gasiorowski, Ph.D. is a Senior Research Scientist for ST Equipment & Teknologi (STET) based in the New Hampshire.

Frank Hrach is Vice President of Process Engineering based at the Separation Technologies pilot plant and lab facility, STET Technical Center, 101 Hampton Ave, Needham MA 02494 +1-781-972-2300